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Low-cost perovskites on rigid glass. Has demonstration 3, cm2 modules. Field tests in progress. Sources: Ref. Oxford PV, for instance, intends to make tandems this year that it says will be one-fifth more efficient than top-end commercial solar panels. If rolled out across the industry, the total power output of solar panels made annually would leap by that same proportion. Saule and other firms, meanwhile, aim to coat plastic with perovskite films to create lightweight, flexible products.
And Swift Solar in San Carlos, California, is trying to combine two different kinds of perovskite cells together to create a lightweight tandem module.
But the quickest route to higher efficiency might be to augment silicon with perovskite. Perovskite can absorb more short-wavelength, blue-green light, leaving the silicon to absorb the longer-wavelength, redder light. These modules will be publicly available by the end of , Case says. Will they last?
The major challenge for perovskites, however, is whether they can last as long as silicon panels, which generally come with a year warranty. His team collaborates on the materials with two large Chinese solar-panel makers, Trina Solar and Suntech.
Commercial solar panels already encapsulate their photovoltaic materials in plastic and glass for protection. This will probably work for most perovskites, too.
A deeper issue lies in the crystals themselves. In some cases, the structures shift as the perovskites warm up; the change is reversible, but it affects performance. The team combines methylammonium and formamidinium cations with small amounts of caesium and rubidium 4 , for example. The combination prevents the structural changes driven by temperature and humidity when individual cations are used.
Most solar technologies have some variations in efficiency, says Kurtz. Credit: Marek Marzejko Still, researchers are making progress. In , for instance, his team reported 5 0. He says his team has now doubled that time in unpublished work. But they all say that they follow a certification standard established for silicon solar panels, set by the International Electrotechnical Commission IEC in Geneva, Switzerland.
If a silicon panel still works after these tests, it is supposed to have a good chance of lasting 25 years in typical weather. But because perovskites have different instabilities from silicon, they could pass these tests and still fail in the real world. All they are is an indication of long-term durability. The firm gets several panels from each manufacturer, puts them through its own set of electrical, optical and temperature tests, and compares results.
The tests are similar to the IEC , but are intended to better capture long-term degradation. Perovskite companies are yet to appear on the lists. Lead toxicity Another potential stumbling block for perovskite cells is that the best of them contain lead, a toxic metal.
Researchers have tried alternatives, such as tin, but performance declines. The analysis also argues that silicon cells have a worse overall environmental impact because of the resources used in their production.
But some researchers say the inclusion of lead rules out the idea of using perovskites in disposable products. There is no compromise on lead toxicity. Credit: Saule Technologies Saule pushes back against that view.
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